@article{oai:nagano-nct.repo.nii.ac.jp:00000084,
 author = {ITAYA, Tomoyuki and 板屋, 智之},
 journal = {長野工業高等専門学校紀要, Memoirs of Nagano National College of Technology},
 month = {Jun},
 note = {application/pdf, The self-assembly of hexakis (4-pyridylmethoxy) cyclotriphosphazene (PyPN) with trimesic acid (TMA) gave rise to supramolecular polymers. Two spramolecular polymers were obtained : 1 from MeOH solution, and 2 from DMF solution. ^1H NMR and elemental analysis showed that the stoichiometry was PyPN/TMA=1:3 for both 1 and 2. From FT-IR and XRD data, it seems that 1 and 2 have the same structure, an alternating sequence of one PyPN and three TMA molecules through hydrogen bonding between pyrudyl unit and carboxylic acid form a rod-shaped polymer with pendant carboxylic groups. In 2, DMF molecules were included at the ratio of DMF/[repeated unit]=1:1. In addition, the inclusion behaviors of Eu^<3+> and Tb^<3+> ions into the crystals of the supramolecular polymers are described.},
 pages = {91--96},
 title = {側鎖にカルボン酸を有するロッド型超分子ポリマーの合成とその金属イオンの取り込み挙動},
 volume = {37},
 year = {2003}
}