{"created":"2023-06-20T15:40:02.391970+00:00","id":84,"links":{},"metadata":{"_buckets":{"deposit":"220b6ab4-4995-45e0-8972-669fc78acbed"},"_deposit":{"created_by":7,"id":"84","owners":[7],"pid":{"revision_id":0,"type":"depid","value":"84"},"status":"published"},"_oai":{"id":"oai:nagano-nct.repo.nii.ac.jp:00000084","sets":["3:13"]},"author_link":["0","0"],"item_2_alternative_title_1":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"Construction of Rod-Shaped Supramolecular Polymers with Pendant Carboxy Groups and Its Inclusion Behavior of Metal Ions"}]},"item_2_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2003-06-30","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"96","bibliographicPageStart":"91","bibliographicVolumeNumber":"37","bibliographic_titles":[{"bibliographic_title":"長野工業高等専門学校紀要"},{"bibliographic_title":"Memoirs of Nagano National College of Technology","bibliographic_titleLang":"en"}]}]},"item_2_creator_3":{"attribute_name":"著者別名","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"ITAYA, Tomoyuki"}],"nameIdentifiers":[{"nameIdentifier":"0","nameIdentifierScheme":"WEKO"}]}]},"item_2_description_19":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_2_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"The self-assembly of hexakis (4-pyridylmethoxy) cyclotriphosphazene (PyPN) with trimesic acid (TMA) gave rise to supramolecular polymers. Two spramolecular polymers were obtained : 1 from MeOH solution, and 2 from DMF solution. ^1H NMR and elemental analysis showed that the stoichiometry was PyPN/TMA=1:3 for both 1 and 2. From FT-IR and XRD data, it seems that 1 and 2 have the same structure, an alternating sequence of one PyPN and three TMA molecules through hydrogen bonding between pyrudyl unit and carboxylic acid form a rod-shaped polymer with pendant carboxylic groups. In 2, DMF molecules were included at the ratio of DMF/[repeated unit]=1:1. In addition, the inclusion behaviors of Eu^<3+> and Tb^<3+> ions into the crystals of the supramolecular polymers are described.","subitem_description_type":"Abstract"}]},"item_2_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"長野工業高等専門学校"}]},"item_2_source_id_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00179170","subitem_source_identifier_type":"NCID"}]},"item_2_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0286-1909","subitem_source_identifier_type":"ISSN"}]},"item_2_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"板屋, 智之"}],"nameIdentifiers":[{"nameIdentifier":"0","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2012-06-01"}],"displaytype":"detail","filename":"KJ00000136642.pdf","filesize":[{"value":"518.7 kB"}],"format":"application/pdf","licensetype":"license_11","mimetype":"application/pdf","url":{"label":"KJ00000136642.pdf","url":"https://nagano-nct.repo.nii.ac.jp/record/84/files/KJ00000136642.pdf"},"version_id":"c7760385-2be4-429f-83ee-09837c2599bf"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"supramolecular polymer","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"hydrogen-bonding","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"inclusion of metal ions","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"側鎖にカルボン酸を有するロッド型超分子ポリマーの合成とその金属イオンの取り込み挙動","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"側鎖にカルボン酸を有するロッド型超分子ポリマーの合成とその金属イオンの取り込み挙動"},{"subitem_title":"Construction of Rod-Shaped Supramolecular Polymers with Pendant Carboxy Groups and Its Inclusion Behavior of Metal Ions","subitem_title_language":"en"}]},"item_type_id":"2","owner":"7","path":["13"],"pubdate":{"attribute_name":"公開日","attribute_value":"2012-06-01"},"publish_date":"2012-06-01","publish_status":"0","recid":"84","relation_version_is_last":true,"title":["側鎖にカルボン酸を有するロッド型超分子ポリマーの合成とその金属イオンの取り込み挙動"],"weko_creator_id":"7","weko_shared_id":7},"updated":"2023-06-20T16:18:50.568935+00:00"}