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側鎖にカルボン酸を有するロッド型超分子ポリマーの合成とその金属イオンの取り込み挙動
https://nagano-nct.repo.nii.ac.jp/records/84
https://nagano-nct.repo.nii.ac.jp/records/847ded9334-4898-485c-8998-b6eca07e3ff2
名前 / ファイル | ライセンス | アクション |
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KJ00000136642.pdf (518.7 kB)
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Item type | Departmental Bulletin Paper(1) | |||||
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公開日 | 2012-06-01 | |||||
タイトル | ||||||
タイトル | 側鎖にカルボン酸を有するロッド型超分子ポリマーの合成とその金属イオンの取り込み挙動 | |||||
タイトル | ||||||
言語 | en | |||||
タイトル | Construction of Rod-Shaped Supramolecular Polymers with Pendant Carboxy Groups and Its Inclusion Behavior of Metal Ions | |||||
言語 | ||||||
言語 | jpn | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | supramolecular polymer | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | hydrogen-bonding | |||||
キーワード | ||||||
言語 | en | |||||
主題Scheme | Other | |||||
主題 | inclusion of metal ions | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
その他(別言語等)のタイトル | ||||||
その他のタイトル | Construction of Rod-Shaped Supramolecular Polymers with Pendant Carboxy Groups and Its Inclusion Behavior of Metal Ions | |||||
著者 |
板屋, 智之
× 板屋, 智之 |
|||||
著者別名 |
ITAYA, Tomoyuki
× ITAYA, Tomoyuki |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | The self-assembly of hexakis (4-pyridylmethoxy) cyclotriphosphazene (PyPN) with trimesic acid (TMA) gave rise to supramolecular polymers. Two spramolecular polymers were obtained : 1 from MeOH solution, and 2 from DMF solution. ^1H NMR and elemental analysis showed that the stoichiometry was PyPN/TMA=1:3 for both 1 and 2. From FT-IR and XRD data, it seems that 1 and 2 have the same structure, an alternating sequence of one PyPN and three TMA molecules through hydrogen bonding between pyrudyl unit and carboxylic acid form a rod-shaped polymer with pendant carboxylic groups. In 2, DMF molecules were included at the ratio of DMF/[repeated unit]=1:1. In addition, the inclusion behaviors of Eu^<3+> and Tb^<3+> ions into the crystals of the supramolecular polymers are described. | |||||
書誌情報 |
長野工業高等専門学校紀要 en : Memoirs of Nagano National College of Technology 巻 37, p. 91-96, 発行日 2003-06-30 |
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出版者 | ||||||
出版者 | 長野工業高等専門学校 | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0286-1909 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AN00179170 | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 |